Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding.
نویسندگان
چکیده
Chemical reduction of a tripodal Cu(II)-F complex containing pendent hydroxyl groups results in the partial dissociation of a F(-) ligand from Cu. The resulting Cu(I) complex is characterized as containing an outer sphere F(-) anion 'captured' by hydrogen bonds. The pendent hydroxyl groups were found to be crucial for reductive stability.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 25 شماره
صفحات -
تاریخ انتشار 2015